Designed synthesis of TS-1 crystals with controllable b-oriented length.

نویسندگان

  • Zhichao Shan
  • Hong Wang
  • Xiangju Meng
  • Siyu Liu
  • Liang Wang
  • Chunyu Wang
  • Fei Li
  • James P Lewis
  • Feng-Shou Xiao
چکیده

TS-1 crystals with controllable b-oriented length (sheet-like morphology, TS-1-S; chain-like morphology, TS-1-C) have been rationally synthesized from addition of organic additives (urea and fluorinated surfactant of FC-4) in the starting titanosilicate gels, and catalytic and adsorptive measurements show that TS-1-S samples are very active in Beckmann rearrangement of cyclohexanone oxime, whereas TS-1-C samples are selective in adsorption for para-xylene.

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عنوان ژورنال:
  • Chemical communications

دوره 47 3  شماره 

صفحات  -

تاریخ انتشار 2011